New synthetic routes to polyoxometal...
Herrmann, Sven.

 

  • New synthetic routes to polyoxometalate containing ionic liquids[electronic resource] :an investigation of their properties /
  • 紀錄類型: 書目-語言資料,印刷品 : Monograph/item
    杜威分類號: 541.2242
    書名/作者: New synthetic routes to polyoxometalate containing ionic liquids : an investigation of their properties // by Sven Herrmann.
    作者: Herrmann, Sven.
    出版者: Wiesbaden : : Springer Fachmedien Wiesbaden :, 2015.
    面頁冊數: xxi, 122 p. : : ill., digital ;; 24 cm.
    Contained By: Springer eBooks
    標題: Polyoxometalates.
    標題: Ionic solutions.
    標題: Chemistry.
    標題: Inorganic Chemistry.
    標題: Catalysis.
    標題: Industrial Chemistry/Chemical Engineering.
    ISBN: 9783658087968 (electronic bk.)
    ISBN: 9783658087951 (paper)
    內容註: Polyoxometlates and Ionic Liquids in General -- POM-Ils as New Class of Compounds -- Synthesis and Characterization of POM-ILs -- Reactivity Towards Azide and Carbonmonoxide.
    摘要、提要註: In his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and Mossbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials.  Contents Polyoxometlates and Ionic Liquids in General POM-Ils as New Class of Compounds Synthesis and Characterization of POM-ILs Reactivity Towards Azide and Carbonmonoxide  Target Groups Researchers and students in the field of chemistry Practitioners in this area  The Author Sven Herrmann obtained his Masters degree at the University of Erlangen-Nürnberg. He then joined the working group of Prof. Carsten Streb in the inorganic department at the University of Ulm to work on his PhD thesis that targets the development of polyoxometalate based ionic liquids (POM-ILs).
    電子資源: http://dx.doi.org/10.1007/978-3-658-08796-8
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