大葉大學圖書館 |

Biomass-derived polymers and copolymers incorporating monolignols and their derivatives.

紀錄類型:	書目-電子資源 : Monograph/item
書名/作者:	Biomass-derived polymers and copolymers incorporating monolignols and their derivatives.
作者:	Upton, Brianna Marie.
出版者:	Ann Arbor : : ProQuest Dissertations & Theses, , 2016
面頁冊數:	255 p.
附註:	Source: Dissertation Abstracts International, Volume: 78-02(E), Section: B.
Contained By:	Dissertation Abstracts International78-02B(E).
標題:	Chemistry.
標題:	Polymer chemistry.
ISBN:	9781369141788
摘要、提要註:	Due to the importance of developing more sustainable commodity materials, this dissertation focuses on the synthesis and characterizarion of a series of polymers and copolymers from monolignols and other biomass components. The polymers described within were designed to feature a modular synthesis and were persued due to their structural similarities to commodity materials. Chapter 2 focuses on the synthetic development, thermal properties, and hydrolytic degradation of a series of monolignols-based poly(ester-amides) via interfacial polymerization with a monolignol-based ester dimer and aliphatic or aromatic diamines. These polymers were found to have differing thermal and degradation properties depending on the length (aliphatic) or structural (aromatic versus aliphatic) characteristics of the diamine utilized. Chapter 3 focuses on the development of the analogous monolignol-based poly(ether-amide) systems. These poly(ether-amide)s were synthesized used a monolignol-based ether dimer and aliphatic or aromatic diamines. As seen previously, the identity of the diamine linker played a role in the observed physical characteristics of the resulting polymers. Finally, Chapter 4 will focus on the development of a series of polymers from monolignols and citraconic anhydride as biologically-derived analogues to petroleum-based polystyrene-co-maleic anhydride and their use in polymer blends with commodity polymers. The monomers were polymerized using BF3Et2O as an initiator in cationic polymerization and the structure and physical properties of the resulting oligomers were then thoroughly studied. The oligomers were then used and studied in polymer blends with polystyrene and poly(lactic-acid). In summary, this dissertation focuses on the synthesis and study of several classes of polymeric materials generated directly from biomass components as chemical sources, with a focus on modularity and the tunability of observed properties.

Biomass-derived polymers and copolymers incorporating monolignols and their derivatives.
Upton, Brianna Marie.

Biomass-derived polymers and copolymers incorporating monolignols and their derivatives. - Ann Arbor : ProQuest Dissertations & Theses, 2016 - 255 p.

Source: Dissertation Abstracts International, Volume: 78-02(E), Section: B.

Thesis (Ph.D.)--University of California, Los Angeles, 2016.

This item is not available from ProQuest Dissertations & Theses.

Due to the importance of developing more sustainable commodity materials, this dissertation focuses on the synthesis and characterizarion of a series of polymers and copolymers from monolignols and other biomass components. The polymers described within were designed to feature a modular synthesis and were persued due to their structural similarities to commodity materials. Chapter 2 focuses on the synthetic development, thermal properties, and hydrolytic degradation of a series of monolignols-based poly(ester-amides) via interfacial polymerization with a monolignol-based ester dimer and aliphatic or aromatic diamines. These polymers were found to have differing thermal and degradation properties depending on the length (aliphatic) or structural (aromatic versus aliphatic) characteristics of the diamine utilized. Chapter 3 focuses on the development of the analogous monolignol-based poly(ether-amide) systems. These poly(ether-amide)s were synthesized used a monolignol-based ether dimer and aliphatic or aromatic diamines. As seen previously, the identity of the diamine linker played a role in the observed physical characteristics of the resulting polymers. Finally, Chapter 4 will focus on the development of a series of polymers from monolignols and citraconic anhydride as biologically-derived analogues to petroleum-based polystyrene-co-maleic anhydride and their use in polymer blends with commodity polymers. The monomers were polymerized using BF3Et2O as an initiator in cationic polymerization and the structure and physical properties of the resulting oligomers were then thoroughly studied. The oligomers were then used and studied in polymer blends with polystyrene and poly(lactic-acid). In summary, this dissertation focuses on the synthesis and study of several classes of polymeric materials generated directly from biomass components as chemical sources, with a focus on modularity and the tunability of observed properties.

ISBN: 9781369141788Subjects--Topical Terms:

182539
Chemistry.

Biomass-derived polymers and copolymers incorporating monolignols and their derivatives.
LDR:02912nmm a2200289 4500 001 476255
005 20170614101409.5
008 181208s2016 ||||||||||||||||| ||eng d
020 $a 9781369141788
035 $a (MiAaPQ)AAI10159187
035 $a AAI10159187
040 $a MiAaPQ $c MiAaPQ
100 1 $a Upton, Brianna Marie. $3 686850
245 1 0 $a Biomass-derived polymers and copolymers incorporating monolignols and their derivatives.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2016
300 $a 255 p.
500 $a Source: Dissertation Abstracts International, Volume: 78-02(E), Section: B.
500 $a Advisers: Andrea M. Kasko; Heather D. Maynard.
502 $a Thesis (Ph.D.)--University of California, Los Angeles, 2016.
506 $a This item is not available from ProQuest Dissertations & Theses.
520 $a Due to the importance of developing more sustainable commodity materials, this dissertation focuses on the synthesis and characterizarion of a series of polymers and copolymers from monolignols and other biomass components. The polymers described within were designed to feature a modular synthesis and were persued due to their structural similarities to commodity materials. Chapter 2 focuses on the synthetic development, thermal properties, and hydrolytic degradation of a series of monolignols-based poly(ester-amides) via interfacial polymerization with a monolignol-based ester dimer and aliphatic or aromatic diamines. These polymers were found to have differing thermal and degradation properties depending on the length (aliphatic) or structural (aromatic versus aliphatic) characteristics of the diamine utilized. Chapter 3 focuses on the development of the analogous monolignol-based poly(ether-amide) systems. These poly(ether-amide)s were synthesized used a monolignol-based ether dimer and aliphatic or aromatic diamines. As seen previously, the identity of the diamine linker played a role in the observed physical characteristics of the resulting polymers. Finally, Chapter 4 will focus on the development of a series of polymers from monolignols and citraconic anhydride as biologically-derived analogues to petroleum-based polystyrene-co-maleic anhydride and their use in polymer blends with commodity polymers. The monomers were polymerized using BF3Et2O as an initiator in cationic polymerization and the structure and physical properties of the resulting oligomers were then thoroughly studied. The oligomers were then used and studied in polymer blends with polystyrene and poly(lactic-acid). In summary, this dissertation focuses on the synthesis and study of several classes of polymeric materials generated directly from biomass components as chemical sources, with a focus on modularity and the tunability of observed properties.
590 $a School code: 0031.
650 4 $a Chemistry. $3 182539
650 4 $a Polymer chemistry. $3 686852
690 $a 0485
690 $a 0495
710 2 0 $a University of California, Los Angeles. $b Chemistry. $3 686851
773 0 $t Dissertation Abstracts International $g 78-02B(E).
790 $a 0031
791 $a Ph.D.
792 $a 2016
793 $a English