Functionalization of carborane via c...
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  • Functionalization of carborane via carboryne intermediates[electronic resource] /
  • 紀錄類型: 書目-電子資源 : Monograph/item
    杜威分類號: 547.05671
    書名/作者: Functionalization of carborane via carboryne intermediates/ by Da Zhao.
    作者: Zhao, Da.
    出版者: Singapore : : Springer Singapore :, 2016.
    面頁冊數: xvii, 170 p. : : ill. (some col.), digital ;; 24 cm.
    Contained By: Springer eBooks
    標題: Carboranes.
    標題: Chemistry.
    標題: Organic Chemistry.
    標題: Physical Chemistry.
    標題: Catalysis.
    ISBN: 9789811015694
    ISBN: 9789811015687
    摘要、提要註: This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal-organic frameworks, electronic devices and more. However, the limited number of efficient synthetic methods for obtaining functional carborane materials has restricted their applications. The methodologies established in this thesis represent simple, yet powerful strategies to assemble previously inaccessible, useful complex molecules, which will also have a significant impact on future synthetic, cluster and materials chemistry. Moreover, it discusses the first method for the in situ generation of electrophilic boron radical using photocatalysis.
    電子資源: http://dx.doi.org/10.1007/978-981-10-1569-4
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