大葉大學圖書館 |

Steric and stereoelectronic effects in organic chemistry[electronic resource] /

紀錄類型:	書目-電子資源 : Monograph/item
杜威分類號:	547.1223
書名/作者:	Steric and stereoelectronic effects in organic chemistry/ by Veejendra K. Yadav.
作者:	Yadav, Veejendra K.
出版者:	Singapore : : Springer Singapore :, 2016.
面頁冊數:	xi, 211 p. : : ill., digital ;; 24 cm.
Contained By:	Springer eBooks
標題:	Stereochemistry.
標題:	Chemistry, Organic.
標題:	Chemistry.
標題:	Organic Chemistry.
標題:	Physical Chemistry.
ISBN:	9789811011399
ISBN:	9789811011382
內容註:	Steric and Stereoelectronic Control of Organic Molecular Structures and Organic Reactions -- Reactions at Saturated and Unsaturated Carbons -- Diastereoselectivity in Organic Reactions -- A(1,2) and A(1,3) Strains -- The Conservation of Orbital Symmetry (Woodward-Hoffmann Rules) -- The Overlap Component of the Stereoelectronic Factor vis-a-vis the Conservation of Orbital Symmetry Rules -- Miscellaneous.
摘要、提要註:	The steric and stereoelectronic effects control the rate and stereochemical outcome of reactions. Hence, a decent understanding of the related concepts is essential for successful synthetic planning. The book attempts to address several important issues related to these concepts in a simplified manner, and is intended for graduate students. It lays stress on the important aspects of steric and stereoelectronic effects and their control on the conformational profile and reactivity features. The book covers the geometrical requirements for reactions at saturated and unsaturated carbons in both cyclic and acyclic systems, and the resultant stereochemical features. The aspect of geometrical flexibility is also covered with a few examples involving intramolecular reactions. It deals with the facial selectivity of nucleophilic additions to acyclic and cyclic carbonyl compounds, and explains how the steric and stereoelectronic effects control the same. The work comments on allylic strains and their stereochemical control on different reactions with the related conformational control. It is a must read to understand the control elements, the prominent among these elements are spiro-conjugation, periselectivity, torquoselectivity, a-effect, Hammett's substituent constants, Hammond postulate, and Curtin-Hammett principle.
電子資源:	http://dx.doi.org/10.1007/978-981-10-1139-9

Steric and stereoelectronic effects in organic chemistry[electronic resource] /
Yadav, Veejendra K.

Steric and stereoelectronic effects in organic chemistry[electronic resource] /by Veejendra K. Yadav. - Singapore :Springer Singapore :2016. - xi, 211 p. :ill., digital ;24 cm.

Steric and Stereoelectronic Control of Organic Molecular Structures and Organic Reactions -- Reactions at Saturated and Unsaturated Carbons -- Diastereoselectivity in Organic Reactions -- A(1,2) and A(1,3) Strains -- The Conservation of Orbital Symmetry (Woodward-Hoffmann Rules) -- The Overlap Component of the Stereoelectronic Factor vis-a-vis the Conservation of Orbital Symmetry Rules -- Miscellaneous.

The steric and stereoelectronic effects control the rate and stereochemical outcome of reactions. Hence, a decent understanding of the related concepts is essential for successful synthetic planning. The book attempts to address several important issues related to these concepts in a simplified manner, and is intended for graduate students. It lays stress on the important aspects of steric and stereoelectronic effects and their control on the conformational profile and reactivity features. The book covers the geometrical requirements for reactions at saturated and unsaturated carbons in both cyclic and acyclic systems, and the resultant stereochemical features. The aspect of geometrical flexibility is also covered with a few examples involving intramolecular reactions. It deals with the facial selectivity of nucleophilic additions to acyclic and cyclic carbonyl compounds, and explains how the steric and stereoelectronic effects control the same. The work comments on allylic strains and their stereochemical control on different reactions with the related conformational control. It is a must read to understand the control elements, the prominent among these elements are spiro-conjugation, periselectivity, torquoselectivity, a-effect, Hammett's substituent constants, Hammond postulate, and Curtin-Hammett principle.

ISBN: 9789811011399

Standard No.: 10.1007/978-981-10-1139-9doiSubjects--Topical Terms:

404126
Stereochemistry.

LC Class. No.: QD481

Dewey Class. No.: 547.1223

Steric and stereoelectronic effects in organic chemistry[electronic resource] /
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520 $a The steric and stereoelectronic effects control the rate and stereochemical outcome of reactions. Hence, a decent understanding of the related concepts is essential for successful synthetic planning. The book attempts to address several important issues related to these concepts in a simplified manner, and is intended for graduate students. It lays stress on the important aspects of steric and stereoelectronic effects and their control on the conformational profile and reactivity features. The book covers the geometrical requirements for reactions at saturated and unsaturated carbons in both cyclic and acyclic systems, and the resultant stereochemical features. The aspect of geometrical flexibility is also covered with a few examples involving intramolecular reactions. It deals with the facial selectivity of nucleophilic additions to acyclic and cyclic carbonyl compounds, and explains how the steric and stereoelectronic effects control the same. The work comments on allylic strains and their stereochemical control on different reactions with the related conformational control. It is a must read to understand the control elements, the prominent among these elements are spiro-conjugation, periselectivity, torquoselectivity, a-effect, Hammett's substituent constants, Hammond postulate, and Curtin-Hammett principle.
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