Bonding in electron-rich molecules[e...
Harcourt, Richard D.

 

  • Bonding in electron-rich molecules[electronic resource] :qualitative valence-bond approach via increased-valence structures /
  • レコード種別: 言語・文字資料 (印刷物) : 単行資料
    [NT 15000414] null: 541.224
    タイトル / 著者: Bonding in electron-rich molecules : qualitative valence-bond approach via increased-valence structures // by Richard D. Harcourt.
    著者: Harcourt, Richard D.
    出版された: Cham : : Springer International Publishing :, 2016.
    記述: xv, 326 p. : : ill., digital ;; 24 cm.
    含まれています: Springer eBooks
    主題: Chemical bonds.
    主題: Chemistry.
    主題: Theoretical and Computational Chemistry.
    主題: Atomic/Molecular Structure and Spectra.
    主題: Organic Chemistry.
    国際標準図書番号 (ISBN) : 9783319166766
    国際標準図書番号 (ISBN) : 9783319166759
    [NT 15000228] null: From the Contents: Atomic Orbitals, Electron Spin, Linear Combinations -- Pauling '3-Electron Bonds', 4-Electron 3-Centre Bonding, and the Need for an 'Increased Valence' Theory -- Wave-Functions and Valence-Bond Structures for 1-Electron Bonds, Electron-Pair Bonds, Pauling '3-Electron Bonds' and 'No Bonds' -- Valence-Bond Structures for Some Diatomic Molecules.
    [NT 15000229] null: This second edition was updated to include some of the recent developments, such as "increased-valence" structures for 3-electron-3-centre bonding, benzene, electron conduction and reaction mechanisms, spiral chain O4 polymers and recoupled-pair bonding. The author provides qualitative molecular orbital and valence-bond descriptions of the electronic structures for primarily electron-rich molecules, with strong emphasis given to the valence-bond approach that uses "increased-valence" structures. He describes how "long-bond" Lewis structures as well as standard Lewis structures are incorporated into "increased-valence" structures for electron-rich molecules. "Increased-valence" structures involve more electrons in bonding than do their component Lewis structures, and are used to provide interpretations for molecular electronic structure, bond properties and reactivities. Attention is also given to Pauling "3-electron bonds", which are usually diatomic components of "increased-valence" structures for electron-rich molecules.
    電子資源: http://dx.doi.org/10.1007/978-3-319-16676-6
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http://dx.doi.org/10.1007/978-3-319-16676-6
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