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Ultrafast dynamics of phospholipid-water interfaces[electronic resource] :studied by nonlinear time-resolved vibrational spectroscopy /

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
杜威分類號:	572.57
書名/作者:	Ultrafast dynamics of phospholipid-water interfaces : studied by nonlinear time-resolved vibrational spectroscopy // by Rene Costard.
作者:	Costard, Rene.
出版者:	Cham : : Springer International Publishing :, 2015.
面頁冊數:	x, 103 p. : : ill., digital ;; 24 cm.
Contained By:	Springer eBooks
標題:	Phospholipids.
標題:	Phospholipids - Spectra.
標題:	Biological interfaces.
標題:	Physics.
標題:	Membranes.
標題:	Physical Chemistry.
標題:	Membrane Biology.
標題:	Atomic/Molecular Structure and Spectra.
標題:	Spectroscopy and Microscopy.
ISBN:	9783319220666
ISBN:	9783319220659
內容註:	Introduction -- Vibrational Spectroscopy -- Ultrafast Vibrational Dynamics of Phospholipid Hydration Sites -- Ultrafast Vibrational Dynamics of Phospholipid Hydration Shells -- Conclusions -- Appendix: Experimental Pulse Parameters.
摘要、提要註:	This thesis presents a highly innovative study of the ultrafast structural and vibrational dynamics of hydrated phospholipids, the basic constituents of cell membranes. As a novel approach to the water-phospholipid interface, the author studies phosphate vibrations using the most advanced methods of nonlinear vibrational spectroscopy, including femtosecond two-dimensional infrared spectroscopy. He shows for the first time that the structure of interfacial water undergoes very limited fluctuations on a 300 fs time scale and that the lifetimes of hydrogen bonds with the phospholipid are typically longer than 10 ps. Such properties originate from the steric hindrance of water fluctuations at the interface and the orienting action of strong electric fields from the phospholipid head group dipoles. In an extensive series of additional experiments, the vibrational lifetimes of the different vibrations and the processes of energy dissipation are elucidated in detail.
電子資源:	http://dx.doi.org/10.1007/978-3-319-22066-6

Ultrafast dynamics of phospholipid-water interfaces[electronic resource] :studied by nonlinear time-resolved vibrational spectroscopy /
Costard, Rene.

Ultrafast dynamics of phospholipid-water interfacesstudied by nonlinear time-resolved vibrational spectroscopy /[electronic resource] :by Rene Costard. - Cham :Springer International Publishing :2015. - x, 103 p. :ill., digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

Introduction -- Vibrational Spectroscopy -- Ultrafast Vibrational Dynamics of Phospholipid Hydration Sites -- Ultrafast Vibrational Dynamics of Phospholipid Hydration Shells -- Conclusions -- Appendix: Experimental Pulse Parameters.

This thesis presents a highly innovative study of the ultrafast structural and vibrational dynamics of hydrated phospholipids, the basic constituents of cell membranes. As a novel approach to the water-phospholipid interface, the author studies phosphate vibrations using the most advanced methods of nonlinear vibrational spectroscopy, including femtosecond two-dimensional infrared spectroscopy. He shows for the first time that the structure of interfacial water undergoes very limited fluctuations on a 300 fs time scale and that the lifetimes of hydrogen bonds with the phospholipid are typically longer than 10 ps. Such properties originate from the steric hindrance of water fluctuations at the interface and the orienting action of strong electric fields from the phospholipid head group dipoles. In an extensive series of additional experiments, the vibrational lifetimes of the different vibrations and the processes of energy dissipation are elucidated in detail.

ISBN: 9783319220666

Standard No.: 10.1007/978-3-319-22066-6doiSubjects--Topical Terms:

634390
Phospholipids.

LC Class. No.: QP752.P53

Dewey Class. No.: 572.57

Ultrafast dynamics of phospholipid-water interfaces[electronic resource] :studied by nonlinear time-resolved vibrational spectroscopy /
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